Tetrahedron

N-Arylation of carbazole by microwave-assisted ligand-free catalytic CuI reaction

JK Kwon, JH Cho, YS Ryu, SH Oh, EK Yum

文献索引：Kwon, Jae Kwan; Cho, Joong Hyun; Ryu, Young-Sil; Oh, Se Hwan; Yum, Eul Kgun Tetrahedron, 2011 , vol. 67, # 26 p. 4820 - 4825

全文：HTML全文

被引用次数: 19

摘要

Abstract N-Arylation of carbazole has been achieved in high yields within 1 h using a microwave-assisted catalytic CuI reaction with no organic ligand. The N-arylation can be performed by various arylhalides, such as phenyl, pyridine, thiophene, and thiazole moieties. Specifically, N-arylated bromocarbazoles were converted into useful synthetic intermediates for functionalized carbazole materials.