Chemistry of anti-o, o'-Dibenzene

…, H Gan, S Halfon, BJ Hrnjez, NC Yang

文献索引：Noh, Taehee; Gan, Hong; Halfon, Sharon; Hrnjez, Bruce J.; Yang, Nien-Chu C. Journal of the American Chemical Society, 1997 , vol. 119, # 32 p. 7470 - 7482

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被引用次数: 22

摘要

A new and efficient preparation of anti-o, o'-dibenzene 1 has been achieved in three steps from cis-3, 5-cyclohexadiene-1, 2-diol 25. Utilizing a method for deoxygenation of 1, 2-diols developed in our laboratory, anti-tetraol 23 was converted to 1 in 65% yield on a 0.5 g scale. This has allowed us to explore the chemistry of anti-dibenzenes extensively. The kinetics for thermal reversion of 1 to benzene have been studied in three different solvents. The direct ...