Green Chemistry

The development of an environmentally benign sulfide oxidation procedure and its assessment by green chemistry metrics

CO Kinen, LI Rossi, RH de Rossi

文献索引：Kinen, Claudio Omar; Rossi, Laura Isabel; De Rossi, Rita Hoyos Green Chemistry, 2009 , vol. 11, # 2 p. 223 - 228

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被引用次数: 19

摘要

Different Iron (III) species were used as catalysts in sulfoxidation reactions giving excellent yields and high chemoselectivity. Among the iron (III) species, the best one was a solid β- cyclodextrin-FeBr3 complex. Sulfoxidation takes place with high chemoselectivity in the presence of other groups such as isothiocyanate. Good results were obtained when these reactions were analyzed using green chemistry metrics.