Tetrahedron

Peracid oxidation and photooxygenation reactions of silacyclopentadienes

MP Mahajan, R Balasubramanian, MV George

文献索引：Mahajan,M.P. et al. Tetrahedron, 1976 , vol. 32, p. 1549 - 1553

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被引用次数: 7

摘要

1-Methyl-1, 2, 3, 4, 5-pentaphenyl-1-silacyclopentadiene on treatment with perbenzoic acid afforded a mixture of products consisting of tetraphenylfuran, cis-dibenzoylstilbene, cis- dibenzoylstilbene epoxide, 2, 5-dihydro-2, 3, 4, 5-tetraphenylfuran, 1, 2, 3-triphenyl-1, 3- propanedione, 1-methylphenylhydroxysilyl-1, 2, 3, 4-tetraphenyl-1, 3-butadiene and cis, cis- 1, 2, 3, 4-tetraphenyl-1, 3-butadiene. Similarly, hexaphenylsilacyclopentadiene reacted ...