The chemical and structural properties of 18 l, 2, 6-thiadiazine 1, l-dioxides have been studied. By comparison with the corresponding pyrazoles it could be established that there are some analogies between pyrazoles and thiadiazine 1, l-dioxides, but because of the great difference in aromaticity, both series of heterocycles behave quite differently in other cases. However, a rough parallelism is observed in the tautomeric equilibrium, the I3C ...