Magnetic Field Effects Observed upon Photolysis of Para-Substituted Diphenyl Disulfides in Micellar Solutions

G Jeschke, M Wakasa, Y Sakaguchi…

文献索引：Jeshke, Gunnar; Wakasa, Masanobu; Sakaguchi, Yoshio; Hayashi, Hisaharu Journal of Physical Chemistry, 1994 , vol. 98, # 15 p. 4069 - 4075

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被引用次数: 25

摘要

The recombination of pairs of para-substituted phenylthiyl radicals inside micellar supercages was studied by means of a nanosecond laser flash photolysis technique. Singlet and triplet pairs were formed by direct excitation and by triplet-sensitized photolysis of the corresponding disulfides, respectively. Magnetic field effects (MFEs) on the yield of escaped thiyl radicals were found for the triplet-sensitized photolysis of the p-amino compound. For ...