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The Journal of Organic Chemistry

Reactions of Aliphatic Methanesulfonates. II. Syntheses of Long-Chain Di-and Trialkyl Glyceryl Ethers1

WJ Baumann, HK Mangold

文献索引:Baumann,W.J.; Mangold,H.K. Journal of Organic Chemistry, 1966 , vol. 31, p. 498 - 500

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被引用次数: 70

摘要

Saturated and unsaturated long-chain dialkyl glyceryl ethers (2, 3-dialkoxy-l-propanols) were syiithesiaed by alkylation of tritylated alkyl glyceryl-(1) ethers (l-alkoxy-3-trityloxy-2- propanols) with methanesulfonates, followed by hydrolytic removal of the trityl groups. Trialkyl glyceryl ethers (1, 2, 3-trialkoxypropanes) containing three identical, or two or three different, alkyl groups were prepared.