Abstract Peptoids are unnatural peptide-like oligomers having the side-chain attached to the glycine nitrogen. In order to investigate how such oligomers are affected upon glycoconjugation, a series of glycosylated peptoids has been synthesized. The conjugation between glycosyl residue and peptoid was achieved by azide+ alkyne [3+ 2] cycloaddition (click reaction). The glycosylated peptoids were obtained by either stepwise assembly ...