Dodecahedryl anion formation and an experimental determination of the acidity and CH bond dissociation energy of dodecahedrane

KM Broadus, SR Kass, T Osswald…

文献索引：Hay,R.S.; Roberts,B.P. Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1978 , p. 770 - 778

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被引用次数: 17

摘要

... Journal of the ... 2000, 122 (44), pp 10964–10968. DOI: 10.1021/ja002588f. Publication Date (Web): October 21, 2000. Copyright © 2000 American Chemical Society. ... and base behavior of 1 and 1a, respectively, enabled the acidity of 1 to be determined (ΔH° acid = 402 ± 2 kcal/mol ...