Tetrahedron

Selenium catalysed oxidations with aqueous hydrogen peroxide. Part 3: Oxidation of carbonyl compounds under mono/bi/triphasic conditions

GJ ten Brink, JM Vis, IWCE Arends, RA Sheldon

文献索引：Ten Brink, Gerd-Jan; Vis, J.Martijn; Arends, Isabel W.C.E; Sheldon, Roger A Tetrahedron, 2002 , vol. 58, # 20 p. 3977 - 3983

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被引用次数: 87

摘要

The total synthesis of 3, 5-bis (perfluorooctyl) phenyl butylselenide (1), a recyclable catalyst for oxidation reactions with hydrogen peroxide, is described. The catalyst can be used for oxidation of aldehydes and ketones under monophasic, but also fluorous biphasic or fluorous triphasic conditions.