Journal of the American Chemical Society

The palladium (II) catalyzed olefin carbonylation reaction. Mechanisms and synthetic utility

DE James, JK Stille

文献索引：James,D.E.; Stille,J.K. Journal of the American Chemical Society, 1976 , vol. 98, # 7 p. 1810 - 1823

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被引用次数: 155

摘要

Abstract: The reaction of carbon monoxide with a variety of cyclic and acyclic olefins at 2-3 atm in methanol in the presence of palladium (I1) chloride and copper (I1) chloride as reoxidant was investigated. Linear a-olefins afforded predominantly (3-methoxy esters under neutral conditions and diesters in the presence of base. Nearly quantitative yields (based on olefin) of these products were realized when greater than stoichiometric amounts of ...