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Bulletin of the Chemical Society of Japan

The thermal decomposition of N, O-diacyl-Nt-butylhydroxylamines. III. Novel routes to 2-substituted 1, 2-benzisothiazol-3-(2H)-ones.

Y Uchida, S Kozuka

文献索引:Uchida; Kozuka Bulletin of the Chemical Society of Japan, 1982 , vol. 55, # 4 p. 1183 - 1187

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被引用次数: 22

摘要

The reactions of N-alkyl-and N-aryl-2-(methylsulfinyl) benzamides and N-[2-(methylthio) benzoyl]-N-alkylhydroxylamines with thionyl chloride have been found to give 2-substituted 1, 2-benzisothiazol-3 (2H)-ones in nearly quantitative yields. The reactions of N-[2- (methylthio) benzoyl]-N-arylhydroxylamines with thionyl chloride gave chlorinated anilides as the major products.