Electronic absorption spectra of some alkoxyl radicals. An experimental and theoretical study

…, AA Di Nardo, F Zerbetto, MZ Zgierski…

文献索引：Avila, David V.; Ingold; Di Nardo, Ariel A.; Zerbetto, Francesco; Zgierski, Marek Z.; Lusztyk, Janusz Journal of the American Chemical Society, 1995 , vol. 117, # 10 p. 2711 - 2718

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被引用次数: 76

摘要

Abstract: The visible and W absorptions of a variety of alkoxyl radicals have been examined by experiment and theory. In most solvents, the tert-butoxyl radical shows only a weak" tail- end'absorption in the UV region of the spectrum and no absorption in the visible region. However, a visible absorption band has been observed (Amu= 440 nm) in the presence of 1, 3, 5-trimethoxybenzene. This absorption band provides the first unequivocal evidence for ...