Selective Iron??Catalyzed Oxidation of Benzylic and Allylic Alcohols

…, A Spannenberg, K Junge, M Beller

文献索引：Schroeder, Kristin; Junge, Kathrin; Spannenberg, Anke; Beller, Matthias Catalysis Today, 2010 , vol. 157, # 1-4 p. 364 - 370

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被引用次数: 28

摘要

Abstract A convenient and selective oxidation of alcohols with hydrogen peroxide to give aldehydes and ketones has been developed. Using in situ generated iron chloride complexes [Fe (L3) 2 Cl n][n= 0–1, L3= 6-(N-phenylbenzimidazoyl)-2-pyridinecarboxylic acid], aldehydes and ketones were obtained in good yield and excellent selectivity after a short reaction time at room temperature.