Organic letters

Intermolecular Antiselective and Enantioselective Reductive Coupling of Enones and Aromatic Aldehydes with Chiral Rh (Phebox) Catalysts

T Shiomi, T Adachi, J Ito, H Nishiyama

文献索引：Lipshutz, Bruce H.; Amorelli, Benjamin; Unger, John B. Journal of the American Chemical Society, 2008 , vol. 130, # 44 p. 14378 - 14379

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被引用次数: 27

摘要

... intermolecular hydrogenative aldol coupling of vinyl ketones catalyzed by [Rh(COD) 2 ]OTf/phosphonite to find high diastereoselectivity to 50:1 and enantioselectivity of 96%.(9) As for the intramolecular coupling, Lipshutz succeeded with ... b 2 h. ... 1. (a) Jang , H.-Y.; Krische , MJ ...