Synthesis, Linear, and Quadratic??Nonlinear Optical Properties of Octupolar D3 and D2d Bipyridyl Metal Complexes

O Maury, L Viau, K Sénéchal, B Corre…

文献索引：Viau, Lydie; Senechal, Katell; Maury, Olivier; Guegan, Jean-Paul; Dupau, Philippe; Toupet, Loic; Le Bozec, Hubert Synthesis, 2003 , # 4 p. 577 - 583

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被引用次数: 127

摘要

Abstract A series of D 3 (Fe II, Ru II, Zn II, Hg II) and D 2d (Cu I, Ag I, Zn II) octupolar metal complexes featuring different functionalized bipyridyl ligands has been synthesized, and their thermal, linear (absorption and emission), and nonlinear optical (NLO) properties were determined. Their quadratic NLO susceptibilities were determined by harmonic light scattering at 1.91 μm, and the molecular hyperpolarizability (β 0) values are in the range ...