From the interaction between azole-type ligands L and AgX (X= NO3 or ClO4) or [AgX (PPh3) n](X= Cl, n= 3; X= MeSO3, n= 2), new ionic mononuclear [Ag (L) 2] X and [Ag (PPh3) 3L][X] or neutral mono-([Ag (PPh3) nL (X)]) or di-nuclear ([{Ag (PPh3)(L)(μ-X)} 2]) complexes have been obtained which have been characterized through elemental analysis, conductivity measurements, IR, 1H NMR and, in some cases, also by 31P {1H} NMR ...