Journal of Molecular Catalysis A: Chemical

Synthesis and characterization of recyclable and recoverable MMT-clay exchanged ammonium tagged carbapalladacycle catalyst for Mizoroki–Heck and …

V Singh, R Ratti, S Kaur

文献索引：Singh, Vasundhara; Ratti, Rajni; Kaur, Sukhbir Journal of Molecular Catalysis A: Chemical, 2011 , vol. 334, # 1-2 p. 13 - 19

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被引用次数: 26

摘要

An efficient synthesis of an ammonium tagged carbapalladacycle 5, in modest yield, has been achieved. Further, the clay-nanocomposite 6 was prepared by ion exchange of 5 into clay interlayers as a new organic–inorganic hybrid catalytic system. The ionic tag of the ammonium supported carbapalladacycle 5 assists in the pillaring process and enhances the organophilicity of catalyst 6 in the interlayers of clay. The catalytic activity in ammonium ...