Mechanism of the substitution reactions of the nineteen-electron cobalt carbonyl complex Co (CO) 3L2 [L2= 2, 3-bis (diphenylphosphino) maleic anhydride]
F Mao, DR Tyler, D Keszler
文献索引：Mao, Fei; Tyler, David R.; Keszler, Doug Journal of the American Chemical Society, 1989 , vol. 111, # 1 p. 130 - 134
Abstract: The substitution reactions of the CO (CO)~ L~ complex [L,= 2, 3-bis (diphenylphosphino) maleic anhydride] with phosphines, phosphites, and iodide were studied. This 19-electron complex (perhaps better described as an 18-electron complex with a reduced ligand) was chosen as a model to study the substitution reactions of more reactive 19-electron complexes. Although a dissociatively activated substitution pathway seemed ...
