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Green Chemistry

Transamidation of amides with amines under solvent-free conditions using a CeO 2 catalyst

M Tamura, T Tonomura, K Shimizu, A Satsuma

文献索引:Tamura, Masazumi; Tonomura, Takuya; Shimizu, Ken-Ichi; Satsuma, Atsushi Green Chemistry, 2012 , vol. 14, # 3 p. 717 - 724

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被引用次数: 94

摘要

Among various metal oxides, cerium oxide (CeO2) shows the highest catalytic activity for transamidation of picolinamide with n-octylamine. CeO2 acts as a reusable and effective heterogeneous catalyst for transamidation under solvent-free conditions. Transamidation of a variety of amides and amines produced the corresponding N-alkyl amides in high yields. This method provides the first example of a heterogeneous catalyst for transamidation ...