The Journal of Organic Chemistry

Scope and pathway of catalytic aminomethylation of olefins

F Jachimowicz, JW Raksis

文献索引：Jachimowicz, Felek; Raksis, Joseph W. Journal of Organic Chemistry, 1982 , vol. 47, # 3 p. 445 - 447

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被引用次数: 46

摘要

We describe a general and high-yield one-step process for synthesis of tertiary and secondary amines from olefins, carbon monoxide, water, and a nitrogen source in the presence of transition-metal compounds tu catalysts. We find this chemistry, initially discovered by W. Reppe, applicable to a wide variety of olefins and nitrogen sources. This chemistry represents a novel general route to secondary and tertiary amines and ...