Macromolecules

Developing a synthetic approach with thermoregulated phase-transfer catalysis: facile access to metal-mediated living radical polymerization of methyl methacrylate in …

L Bai, L Zhang, J Pan, J Zhu, Z Cheng, X Zhu

文献索引：Bai, Liangjiu; Zhang, Lifen; Pan, Jinlong; Zhu, Jian; Cheng, Zhenping; Zhu, Xiulin Macromolecules, 2013 , vol. 46, # 6 p. 2060 - 2066

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被引用次数: 35

摘要

A novel strategy via thermoregulated phase-transfer catalysis (TRPTC) to separating catalyst in aqueous/organic biphasic system has been successfully established in a copper- mediated activators generated by electron transfer for atom transfer radical polymerization (AGET ATRP) of methyl methacrylate (MMA), using a thermoresponsive PEG-supported dipyridyl ligand (PSDL) as the ligand and an alkyl pseudohalogen 2-cyanoprop-2-yl 1- ...