Nucleophilic micelles. II. Effect on the rate of solvolysis of neutral, positively, and negatively charged esters of varied chain length when incorporated into nonfunctional …
TC Bruice, J Katzhendler, LR Fedor
文献索引：Bruice,T.C. et al. Journal of the American Chemical Society, 1968 , vol. 90, p. 1333 - 1348
Abstract: Phenyl esters of carboxylic acids of varied chain length have been synthesized (compounds I-IV). The phenyl head groups of esters I-IV possess the charged groups- N+(CH& and-SO3-para to the ester moiety. The rate constants for the alkaline hydrolysis of esters I-IV were determined in the absence and presence of the neutral, negatively, and positively charged micelle-forming agents of VIII. The second-order rate constants for ...
