Journal of molecular structure

Raman and infrared spectra, structure, vibrational assignment, normal coordinate analysis, and ab initio calculations of trifluoromethyl isocyanate

JR Durig, GA Guirgis, S Eltayeb

文献索引：Durig, J. R.; Guirgis, G. A.; Eltayeb, S. Journal of Molecular Structure, 1994 , vol. 324, p. 93 - 106

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被引用次数: 10

摘要

Abstract The Raman (2500 to 30 cm− 1) and infrared (2500 to 60 cm 1) spectra of gaseous and solid trifluoromethyl isocyanate, CF 3 NCO, have been recorded. The Raman spectrum of the liquid has also been obtained and qualitative depolarization ratios have been measured. The CNC bend has been observed in the low-frequency Raman spectrum of the gas at 130 cm− 1 as a relatively strong line which is split in the spectrum of the solid. ...