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Tetrahedron Letters

Synthesis and self-assembling behavior of a porphyrin bearing multiple meso-conjugated barbiturates

S Arai, T Okamura, S Takeoka

文献索引:Arai, Satoshi; Okamura, Toshiya; Takeoka, Shinji Tetrahedron Letters, 2010 , vol. 51, # 39 p. 5177 - 5180

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被引用次数: 4

摘要

An efficient procedure through deprotection of 2, 4, 6-trimethoxypyrimidine derivative afforded porphyrinato zinc bearing multi-barbiturates acting as multiple hydrogen bonding sites at the meso positions. Addition of excess amphiphilic triaminopyrimidine derivative, as a complementary motif to the barbiturate, in an aqueous solution of porphyrin conjugated with multiple barbiturates at the meso positions resulted in precipitation. The cast film from ...