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Macromolecules

Synthesis and comparison of hyperbranched aromatic polyimides having the same repeating unit by AB2 self-polymerization and A2+ B3 polymerization

J Hao, M Jikei, M Kakimoto

文献索引:Hao, Jianjun; Jikei, Mitsutoshi; Kakimoto, Masa-Aki Macromolecules, 2003 , vol. 36, # 10 p. 3519 - 3528

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被引用次数: 118

摘要

A new AB2 monomer, designed from a template of the repeating unit of the hyperbranched polyimides by nonideal A2+ B3 polymerization, was successfully prepared via a multistep synthesis. Hyperbranched polyimides, having the same repeating unit as that by nonideal A2+ B3 polymerization, were prepared from this new AB2 monomer by direct self- polycondensation in the presence of diphenyl (2, 3-dihydro-2-thioxo-3-benzoxazolyl) ...