The products of the reaction of thiiranium ions with competing nucleophiles

GH Schmid, M Strukelj, S Dalipi

文献索引：Schmid, George H.; Strukelj, Mark; Dalipi, Snezana Canadian Journal of Chemistry, 1987 , vol. 65, p. 1945 - 1950

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被引用次数: 6

摘要

The reaction of the stable thiiranium ion, prepared by the reaction of trifluoromethanesulfonic acid and methyl-3-(4-chlorophenylthio) propene with tetraethylammonium chloride in either 3.5 or 36% v/v methanol/dichloromethane with urea as a buffer, forms 2-methoxy-2-methyl-1- propyl 4-chlorophenyl sulfide, 2-chloro-2-methyl-1-propyl 4-chlorophenyl sulfide, and 1- chloro-2-methyl-2-propyl 4-chlorophenyl sulfide as products. While these same products ...