Synthesis and Coordination Properties of Nitrogen (I)??Based Ligands

H Bruns, M Patil, J Carreras, A Vázquez…

文献索引：Bruns, Hans; Patil, Mahendra; Carreras, Javier; Vazquez, Arcadio; Thiel, Walter; Goddard, Richard; Alcarazo, Manuel Angewandte Chemie - International Edition, 2010 , vol. 49, # 21 p. 3680 - 3683

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被引用次数: 42

摘要

In most organic compounds, nitrogen uses three of its five valence electrons to form bonds with surrounding atoms whilst keeping the other two as a lone pair. Similarly, with the exception of carbon monoxide, carbenes, and isonitriles, carbon is normally tetravalent in organic molecules. However, following seminal work from Ramírez [1] and inspiring theoretical studies from Frenking,[2] Bertrand [3] and Fürstner [4] have synthesized and ...