Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... The regioselective S → C and S → N allylic rearrangements of S-allylthioimidates are realized by thermolysis (l60∼200°C) or palladium (II) catalysis (l∼l0 mol% in refluxing THF), respectively. ... Org. Syntheses, VWiley, New York, NY (1973), p. 780 Coll.