Sterically hindered 4-hydroxybenzenesulfenyl chloride: reactivity with trivalent phosphorus esters
…, JD Spivack, LP Steinhuebel, PA Odorisio
文献索引：Pastor, Stephen D.; Spivack, John D.; Steinhuebel, Leander P.; Odorisio, Paul A. Phosphorus and Sulfur and the Related Elements, 1987 , vol. 29, p. 31 - 34
Abstract The reaction of 3, 5-di-tert-butyl-4-hydroxybenzenesulfenyl chloride, 1, with the trialkyl phosphites 5a–d gave the corresponding S-(3, 5-di-tert-butyl-4-hydroxyphenyl)-O, O- dialkyl phosphorothiolates 6a–d. The formation of 6a–d constitutes chemical evidence for the intermediacy of 1 which was previously inferred from spectroscopic evidence.
