The synthesis of non??symmetrical stilbene analogs of trans??resveratrol using the same Pd catalyst in a sequential double??Heck arylation of ethylene

…, M Seferin, WM da Silva, AL Monteiro

文献索引：Nobre, Sabrina M.; Muniz, Mauro N.; Seferin, Marcus; Da Silva, Wagner M.; Monteiro, Adriano L. Applied Organometallic Chemistry, 2011 , vol. 25, # 4 p. 289 - 293

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被引用次数: 10

摘要

Abstract We have developed a sequential and selective Pd-catalyzed double-Heck arylation of ethylene that results in non-symmetrical nitro-stilbene analogs of trans-resveratrol at excellent yields. A catalytic system consisting of Pd (OAc) 2 and P (o-tolyl) 3 permitted us to carry out the two consecutive Heck arylations without losing activity from the first to the second Heck reaction. After the first Heck arylation of ethylene, no isolation or additional ...