Palladium??Catalyzed Carbonylation/Acyl Migratory Insertion Sequence

…, M Gong, X Zhao, Y Zhang, J Wang

文献索引：Zhang, Zhenhua; Liu, Yiyang; Gong, Mingxing; Zhao, Xiaokun; Zhang, Yan; Wang, Jianbo Angewandte Chemie - International Edition, 2010 , vol. 49, # 6 p. 1139 - 1142

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被引用次数: 89

摘要

Migratory insertion is one of the fundamental processes in organopalladium chemistry. In particular, migratory insertion of a CO ligand and the formation of reactive acylpalladium intermediate is a powerful method for introducing a carbonyl functionality into organic molecules. The catalytic cycle involving such a key step has been developed into one of the most important tools to synthesize various carbonyl compounds.[1] However, for a long ...