Canadian Journal of Chemistry

The bromination-methanolysis of N-acetyl-2, 3-dimethylindole

SF Vice, GI Dmitrienko

文献索引：Vice, Susan F.; Dmitrienko, Gary I. Canadian Journal of Chemistry, 1982 , vol. 60, p. 1233 - 1237

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被引用次数: 6

摘要

Bromination of N-acetyl-2, 3-dimethylindole 11 in the presence of excess methanol at room temperature gave a mixture of products consisting of cis and trans N-acetyl-2, 3-dimethoxy- 2, 3-dimethylindoline 17 and 18, 3-methoxy-2, 3-dimethylindolenine 19, and N-acetyl-3- methoxymethyl-2-methylindole 21. The same reaction performed at-40° C yielded a mixture of 17, 18, and N-acetyl-2-methoxy-2-methyl-3-methyleneindoline 22. Bromination of 11 at ...