Synthesis

Facile one-pot synthesis of di-and tri-substituted furans from acyl isocyanates using trimethylsilyldiazomethane

Y Hari, T Iguchi, T Aoyama

文献索引：Hari, Yoshiyuki; Iguchi, Tomoe; Aoyama, Toyohiko Synthesis, 2004 , # 9 p. 1359 - 1362

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被引用次数: 7

摘要

Abstract The Diels-Alder reaction of 2-substituted 4-(trimethylsilyloxy) oxazoles, which were prepared in situ from trimethylsilyldiazomethane and acyl isocyanates, with dimethyl acetylenedicarboxylate or ethyl propiolate gave furan-3, 4-dicarboxylic or furan-3-carboxylic esters in good yields.