Journal of the American Chemical Society

Transition-metal-catalyzed immobilization of organic functional groups onto solid supports through vinylsilane coupling reactions

JW Park, CH Jun

文献索引：Park, Jung-Woo; Jun, Chul-Ho Journal of the American Chemical Society, 2010 , vol. 132, # 21 p. 7268 - 7269

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被引用次数: 17

摘要

A novel and efficient grafting method for covalent bonding of functional organic molecules to silica or glass surfaces has been developed. The protocol employs transition-metal- catalyzed reactions of vinylsilanes with surface hydroxyl groups. Dimethyldivinylsilane can be used in this procedure as a linker in which one vinyl group is used for direct C− C bond formation with a functional organic molecule and the other is employed to immobilize the ...