Optical properties of spiroconjugated charge-transfer dyes

…, R Wortmann, S Lebus, AL Rheingold…

文献索引：Maslak, Przemyslaw; Chopra, Anu; Moylan, Christopher R.; Wortmann, Ruediger; Lebus, Sonja; Rheingold, Arnold L.; Yap, Glenn P. A. Journal of the American Chemical Society, 1996 , vol. 118, # 6 p. 1471 - 1481

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被引用次数: 58

摘要

A new type of intramolecular charge-transfer dye has been prepared. The LUMO of the acceptor part (1, 3-indandione) in these compounds is spiroconjugated with the HOMO of the donor part (aromatic diamine or amino thiol). The interaction between the donor and acceptor is controlled by the energy and symmetry of the frontier orbitals. The ground state dipole moments of these compounds are aligned along the long molecular axes. In the ...