Tetrahedron letters

Synthesis of alkenyl-and alkynylcyclopropenes

MM Haley, B Biggs, WA Looney, RD Gilbertson

文献索引：Haley, Michael M.; Biggs, Bluegrass; Looney, Will A.; Gilbertson, Robert D. Tetrahedron Letters, 1995 , vol. 36, # 20 p. 3457 - 3460

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被引用次数: 18

摘要

Fluoride anion promoted dehalosilation of 2-(chlorocyclopropyl) trimethylsilanes in the gas- phase was used to prepare a variety of monosubstituted cyclopropenes containing additional unsaturations. The cyclopropylsilanes were constructed easily from common intermediates.