The Journal of Organic Chemistry

Steric effects on the reaction of propargyl and allenyl chlorodies with sodium methoxide in methanol

TL Jacobs, S Hoff

文献索引：Jacobs,T.L.; Hoff,S. Journal of Organic Chemistry, 1968 , vol. 33, p. 2986 - 2988

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被引用次数: 1

摘要

The halide mixtures were obtained by treatment of the propargyl alcohols, 11, with hydrochloric acid, calcium chloride, and copper bronze6 (see Table 11). Attempts were made to increase the proportions of IV by rearrangement with a mixture of ammonium chloride, hydrochloric acid, cuprous chloride, and copper powder, but no change was observed. When the cuprous chloride and copper bronze were omitted from the reaction ...