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Green Chemistry

A recyclable triethylammonium ion-tagged diphenylphosphine palladium complex for the Suzuki–Miyaura reaction in ionic liquids

M Lombardo, M Chiarucci, C Trombini

文献索引:Lombardo, Marco; Chiarucci, Michel; Trombini, Claudio Green Chemistry, 2009 , vol. 11, # 4 p. 574 - 579

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被引用次数: 50

摘要

Suzuki-Miyaura reactions of aryl bromides and arylboronic acids proceed in good to excellent yields in a pyrrolidinium ionic liquid by using a preformed air stable and easily handled triethylammonium-tagged diphenylphosphine palladium (II) complex (2). The reaction requires short reaction times and mild temperature conditions and does not show any tendency towards the formation of palladium black. After extraction of the product, the ...