Activating Multistep Charge-Transfer Processes in Fullerene− Subphthalocyanine− Ferrocene Molecular Hybrids as a Function of π− π Orbital Overlap

D González-Rodríguez, E Carbonell…

文献索引：Gonzalez-Rodriguez, David; Carbonell, Esther; Rojas, Gustavo De Miguel; Castellanos, Carmen Atienza; Guldi, Dirk M.; Torres, Tomas Journal of the American Chemical Society, 2010 , vol. 132, # 46 p. 16488 - 16500

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被引用次数: 52

摘要

We have synthesized two different fullerene− subphthalocyanine− ferrocene conjugates. The molecules were designed so that the ferrocene unit is linked at the subphthalocyanine axial position through a phenoxy spacer while the C60 is rigidly held close to the concave face of the macrocycle via a 3-fold C 3-symmetrical anchoring. The Bingel trisaddition reaction leading to the final products proceeded with very high regioselectivities and full ...