Sila-Substitution of Alkyl Nitrates: Synthesis, Structural Characterization, and Sensitivity Studies of Highly Explosive (Nitratomethyl)-, Bis (nitratomethyl)-, and Tris ( …

C Evangelisti, TM Klapötke, B Krumm…

文献索引：Evangelisti, Camilla; Klapoetke, Thomas M.; Krumm, Burkhard; Nieder, Anian; Berger, Raphael J.F.; Hayes, Stuart A.; Mitzel, Norbert W.; Troegel, Dennis; Tacke, Reinhold Inorganic Chemistry, 2010 , vol. 49, # 11 p. 4865 - 4880

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被引用次数: 15

摘要

A series of analogous nitratomethyl compounds of carbon and silicon of the formula types Me3ElCH2ONO2 (1a/1b), Me2El (CH2ONO2) 2 (2a/2b), MeEl (CH2ONO2) 3 (3a/3b),(CH2) 4El (CH2ONO2) 2 (4a/4b), and (CH2) 5El (CH2ONO2) 2 (5a/5b) were synthesized [El= C (a), Si (b);(CH2) 4El=(sila) cyclopentane-1, 1-diyl;(CH2) 5El=(sila) cyclohexane-1, 1-diyl]. All compounds were characterized by using NMR, IR, and Raman spectroscopy and mass ...