Synthesis and structures of free and coordinated phosphaalkenes

…, JG Lasch, NC Norman, CA Stewart…

文献索引：Cowley, A. H.; Jones, R. A.; Lasch, J. G.; Norman, N. C.; Stewart, C. A.; et al. Journal of the American Chemical Society, 1984 , vol. 106, # 23 p. 7015 - 7020

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被引用次数: 52

摘要

Abstract: Treatment of (Me3P), NiCI2 with [(Me3Si), CHI2PNa affords the q2-phosphaalkene complex (Me3P) 2Ni-[(Me, Si), CPC (H)(SiMe,),](1). The structure of 1 has been determined by single-crystal X-ray diffraction. Compound 1 crystallizes in the space group P21/c with Z= 4 and a= 8.742 (6) A, b= 19.225 (6) A, c= 20.11 1 (8) A, and@= 99.21