Journal of the American Chemical Society

Condensation of Saturated Halides with Unsaturated Compounds. IV. Condensation of t-Butyl Chloride with Cyclohexene1

L Schmerling

文献索引：Schmerling Journal of the American Chemical Society, 1947 , vol. 69, p. 1121,1123

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被引用次数: 18

摘要

Condensation of t-butyl chloride with cyclohexene yielded very little, if any, of the product (1- chloro-2-t-butylcyclohexane, I) to be expected by the simple addition of the alkyl group and the halogen atom to the doubly-bonded carbon atoms of the cycloolefin. Instead, the principal product was either 1-chloro-1-t-butylcyclohexane (11) or 1-chloro-3-t- butylcyclohexane (111) depending on the catalyst used. Thus, in the presence of ...