Synlett

Catalytic Hydrophosphination of alkenylalkyl ethers

MA Kazankova, MO Shulyupin, IP Beletskaya

文献索引：Kazankova, Marina A.; Shulyupin, Mstislav O.; Beletskaya, Irina P. Synlett, 2003 , # 14 p. 2155 - 2158

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被引用次数: 12

摘要

Recently we have performed hydrophosphination of styrenes and heteroanalogs of styrene catalyzed by Pd- and Ni-complexes and have shown that Ni-complexes are more active than Pd-complexes. [7] In all reaction only anti-Markovnikov products - β-isomers were formed. Apparently aryl groups activate the double bond because alkylalkenes failed to react with Ph 2 PH under these conditions. We suppose that this reaction can be considered as a catalytic analog ...