Canadian Journal of Chemistry

Carbonyl addition reactions: Factors affecting the hydrate-hemiacetal and hemiacetal-acetal equilibrium constants

JP Guthrie

文献索引：Linderman, Russel J.; Lonikar, Madhu S. Tetrahedron Letters, 1987 , vol. 28, # 44 p. 5271 - 5274

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被引用次数: 167

摘要

... It should also be noted that the steric corrections can be as large as a factor of 28 in K,". Sander and Jencks (13) have proposed the linear free energy relation for addition of nucleophiles to carbonyl com- pounds. In this equation, A and A are constants ... 904 CAN. J. CHEM. VOL. ...