New polyethylene based anion exchange membranes (PE–AEMs) with high ionic conductivity

M Zhang, HK Kim, E Chalkova, F Mark, SN Lvov…

文献索引：Zhang, Min; Kim, Hyung Kyu; Chalkova, Elena; Mark, Fedkin; Lvov, Serguei N.; Chung, T. C. Mike Macromolecules, 2011 , vol. 44, # 15 p. 5937 - 5946

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被引用次数: 56

摘要

This paper discusses a new class of high performance polyethylene-based anion exchange membranes (PE–AEMs) that contain a wide concentration range of pendant (flexible) ammonium chloride (NR3+ Cl–) groups and with or without a cross-linked PE matrix structure. The chemistry involves a metallocene-mediated polymerization of ethylene, silane- protected α, ω-amino-olefin [C x N (SiMe3) 2], with or without styrenic diene (cross-linker), ...