Monatshefte für Chemie/Chemical Monthly

Über die Synthese von substituierten 2-Aminopyrrolinen, 2. Mitt.

W Klötzer

文献索引：Kloetzer,W. Monatshefte fuer Chemie, 1970 , vol. 101, p. 1841 - 1850

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被引用次数: 4

摘要

Abstract Geminal dimethyl substituted N-acylaziridines react with diphenylacetonitrite (as anion), the course of the reaction depending on the nature of the acyl group. N-carbethoxy- 2.2-dimethylaziridine undergoes abnormal aziridine ring opening at the gem.-substituted C atom and migration of the carbethoxy group accompanied by 5-membered ring closure to yield as major product N-2-carbethoxylamino-3.3-diphenyl-4.4-dimethylpyrroline-1 (1). In ...