Chemical Communications

Ortho-C–H borylation of benzoate esters with bis (pinacolato) diboron catalyzed by iridium–phosphine complexes

T Ishiyama, H Isou, T Kikuchi, N Miyaura

文献索引：Ishiyama, Tatsuo; Isou, Hironori; Kikuchi, Takao; Miyaura, Norio Chemical Communications, 2010 , vol. 46, # 1 p. 159 - 161

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被引用次数: 78

摘要

Iridium complexes generated from [Ir (OMe)(COD)] 2 and tris [3, 5-bis (trifluoromethyl) phenyl] phosphine efficiently catalyzed the ortho-C–H borylation of benzoate esters with bis (pinacolato) diboron in octane at 80° C to produce the corresponding arylboronates in high yields with excellent regioselectivities.