Spectroscopic and calorimetric studies on the mechanism of methylenecyclopropane rearrangements triggered by photoinduced electron transfer
…, A Houmam, DDM Wayner, S Tero-Kubota…
文献索引：Ikeda; Nakamura; Miyashi; Goodman; Akiyama; Tero-Kubota; Houmam; Wayner Journal of the American Chemical Society, 1998 , vol. 120, # 23 p. 5832 - 5833
2-(Dideuteriomethylene)-1, 1-bis (4-methoxyphenyl) cyclopropane (d 2-1) undergoes degenerate rearrangement in both singlet-and triplet-sensitized electron-transfer photoreactions. Nanosecond time-resolved absorption spectroscopy on laser flash photolysis of the unlabeled 1 with 9, 10-dicyanoanthracene, 1, 2, 4, 5-tetracyanobenzene, or N-methylquinolinium tetrafluoroborate as an electron-accepting photosensitizer gives rise ...
