Preparation and ESR detection of a ground-state nonet hydrocarbon as a model for one-dimensional organic ferromagnets

…, K Itoh, H Iwamura, K Kobayashi

文献索引：Teki, Yoshio; Takui, Takeji; Itoh, Koichi; Iwamura, Hiizu; Kobayashi, Kazumasa Journal of the American Chemical Society, 1983 , vol. 105, # 11 p. 3722 - 3723

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被引用次数: 227

摘要

Abstract: The spin state and molecular conformation of a novel alternant hydrocarbon, m- phenylenebis [(diphenyl-methylen-3-yl) methylene](I), have been studied by electron-spin resonance. The tetracarbene 1 was generated by the photolysis of the corresponding tetradiazo compound, m-phenylenebis [m-(a-diazobenzyl) phenyldiazomethane](2), which was synthesized as follows: The reaction of m-tolylmagnesium bromide with ...